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Pulsed NMR
introduction | the instrument | experiments
| specifications| prices
New Pulsed/CW NMR Designed for Teaching
TeachSpin’s Pulsed NMR is THE instrument to help students understand how
the data delivered by sophisticated research or commercial apparatus is produced.
TeachSpin's Pulsed NMR Spectrometer Includes:
- a permanent magnet
- a crossed-coil sample probe
- and three electronic modules:
- a pulse programmer
- an oscillator/power amplifier/mixer
- and a receiver
- The pulse programmer creates the appropriate pulse stream.
- The synthesized continuous-wave (CW) 15MHz oscillator is modulated
into microsecond pulse bursts by the pulse stream. The stable
oscillator can be tuned to the resonant frequency of the sample
protons in the magnetic field.
- The rf power amplifier creates large rotating B fields at the
sample so that a 90° pulse requires a pulse of only 5µs
duration.
- The receiver amplifies the small rf signal created by the precessing
nuclear magnetization. The rf signal can then be demodulated by
either the linear amplitude detector or by the mixer phase-sensitive
detector. The mixer obtains its reference signal directly from
the CW oscillator.
- The free-precession decay and the spin-echo signals can be measured using either a digital or analog oscilloscope.
Special Features Designed for Teaching
- A crossed-coil probe is used so that the students
can see how the pulsed oscillator and the receiver function independently.
- The instrument is composed of three independent units, an oscillator-amplifier,
a pulse programmer and a receiver.
- All the connections between the modules and the crossed-coil probe
are made by the students on the front panel with
coaxial cables. This allows students to understand what the hardware
is doing. Errors in connecting cannot damage the instrument.
- External BNC connectors allow students to interrogate
of each module independently.
- Students use the Oscillator/Amplifier to hand
adjust the frequency of the rf pulse to match the free precession
frequency of the nucleus they are investigating.
- Students directly connect the Pulse Programmer
to the Oscillator and recognize that it controls the timing of
the radio frequency pulses.
- With the Pulse Programmer, students select the
duration, number, spacing and repetition rate of the rf pulses.
The student, not a well programmed computer, makes the choices.
Mistakes, which highlight misconceptions, are easily corrected.
- Watching the effect of varying the pulse width from 0 to more
than 360 degrees makes some of the adjustments done automatically
in research instruments more comprehensible.
- Reducing the repetition time until the signal shrinks illustrates
the meaning of T1.
- Students can monitor either the actual simple
harmonic signal of the rf spins or the traditional Envelope of
the Free Induction Decay. (In our demonstrations, we find the
distinction is not always obvious in spite of textbook knowledge.)
- Apparent changes in T2 due to self diffusion can be examined by
monitoring the effect of changing delay time in a multi-pulse
Carr-Purcell sequence.
- Students actually take raw data of voltage and time which they
can plot in a variety of ways rather than just using the print
out of an automated machine. This means they can better understand
the calculations and graphs a research apparatus might supply.
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